Energy structure of CdSe/CdTe type II colloidal quantum dots—Do phonon bottlenecks remain for thick shells?

Type-II Colloidal Quantum Wells: CdSe/CdTe Core/Crown Heteronanoplatelets

Solution-processed quantum wells, also known as colloidal nanoplatelets (NPLs), are emerging as promising materials for colloidal optoelectronics. In this work, we report the synthesis and characterization of CdSe/CdTe core/crown NPLs exhibiting a Type-II electronic structure and Type-II specific optical properties. Here, based on a core-seeded approach, the CdSe/CdTe core/crown NPLs were synth...

Tailoring the phonon band structure in binary colloidal mixtures.

We analyze the phonon spectra of periodic structures formed by two-dimensional mixtures of dipolar colloidal particles. These mixtures display an enormous variety of complex ordered configurations [J. Fornleitner, Soft Matter 4, 480 (2008)], allowing for the systematic investigation of the ensuing phonon spectra and the control of phononic gaps. We show how the shape of the phonon bands and the...

Competition between zero-phonon and phonon-assisted luminescence in colloidal CdSe quantum dots

Wavefunction engineering: From quantum wells to near-infrared type-II colloidal quantum dots synthesized by layer-by-layer colloidal epitaxy.

We review the concept and the evolution of bandgap and wavefunction engineering, the seminal contributions of Dr. Chemla to the understanding of the rich phenomena displayed in epitaxially grown quantum confined systems, and demonstrate the application of these concepts to the colloidal synthesis of high quality type-II CdTe/CdSe quantum dots using successive ion layer adsorption and reaction c...

Generation and Fracturing of Thick Shells

In this paper we present methods to generate and animate shells with a pre-defined thickness. Given a polygonal surface mesh, a thick shell is constructed by computing a second, extruded polygonal surface. We introduce methods to simulate deformation and fracture of thick shells in realtime. Mass-spring models are used in this context. A novel simulation framework to generate, animate and inter...